N-(3,4-Dimethoxyphenyl)-4-oxo-2,3,7-triazaspiro[4.5]dec-1-ene-1-carboxamide Hydrochloride

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In the title compound, C(13)H(17)ClN(2)O, the piperidine ring adopts a chair conformation and the N atom in that ring is close to pyramidal (bond angle sum = 357.5°). In the crystal, mol-ecules are linked into C(4) chains propagating in [010] by N-H⋯O hydrogen bonds.

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2,6-Dimethyl-4-oxo-3-oxatri­cyclo­[5.2.1.02,6]decane-1-carboxamide

In the title compound, C12H17NO3, which was synthesized by Wagner-Meerwein rearrangement of the N-nitro-imine, the ring-junction C-C bond length is comparatively long [1.573 (2) Å] due to a steric repulsion between the methyl groups at these atoms, which also leads to an increase in the C-C-C angles along this C4 chain [118.10 (13) and 115.04 (15) °, respectively]. In the crystal, N-H⋯O-C and N...

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trans-Tetra­kis[N-(adamantan-1-yl)pyridine-4-carboxamide]­dichlorido­manganese(II)–N-(adamantan-1-yl)pyridine-4-carboxamide (1/2)

The asymmetric unit of the title compound, [MnCl(2)(C(16)H(20)N(2)O)(4)]·2C(16)H(20)N(2)O, is composed of two coordinating N-(adamantan-1-yl)pyridine-4-carboxamide mol-ecules, one Cl(-) anion, an Mn(II) ion, lying on an inversion centre, and one free N-(adamantan-1-yl)pyridine-4-carboxamide mol-ecule. The distorted octa-hedral Mn environment comprises two terminal Cl atoms and four monodentate ...

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ژورنال

عنوان ژورنال: Molbank

سال: 2012

ISSN: 1422-8599

DOI: 10.3390/m769